- Can be charged and discharged over 12,000
times without degradation
- Extremely low self discharge
- Sized up to tens of megawatt hours
- Designed for unattended operation with
very low maintenance
- Can be easily upgraded with more capacity
- Applications include:
- load leveling
- utility ancillary services
- electrical power arbitrage
- renewable energy capacity
support (wind and solar power).
The Vanadium Redox Battery Energy Storage
System (VRB-ESS) is an electrical energy storage
system based on the patented vanadium-based
redox regenerative fuel cell that converts
chemical energy into electrical energy. Energy
is stored chemically in different ionic forms
of vanadium in a dilute sulfuric acid electrolyte.
The electrolyte is pumped from separate plastic
storage tanks into the flow cells across a
proton exchange membrane (PEM) where one form
of electrolyte is electrochemically oxidized
and the other is electrochemically reduced.
This creates a current that is collected by
electrodes and made available to an external
circuit. The reaction is reversible allowing
the battery to be charged, discharged and
recharged, tens of thousands of times throughout
the life cycle.
The principle of the VRB is shown in more
detail in Figure 1 – it consists of
two electrolyte tanks, each containing active
vanadium electrolyte charged to opposite states.
These energy-bearing liquids are circulated
in the cell stack by pumps. The stack consists
of many cells connected in series, each of
which contains two half-cells that are separated
by a membrane. The electrochemical reactions
in the half-cells take place on inert carbon
felt polymer composite electrodes from which
current may be used to charge or discharge
the battery.
The VRB employs vanadium ions in both half-cell
electrolytes. Therefore, cross-contamination
of ions through the membrane separator has
no detrimental influence on the battery capacity,
as is the case in redox flow batteries employing
different metal species in the positive and
negative half-cells. The vanadium half-cell
solutions can even be remixed bringing the
system back to its original state.
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